| 1. A Man Alone - John Barry & His Orchestra | |
| 2. Deadlier Than The Male - The Walker Brothers | |
| 3. Arabesque - The Ventures | |
| 4. The Look Of Love - Dusty Springfield | |
| 5. Danger Man - Red Price & His Combo | |
| 6. The Silencers - Vikki Carr | |
| 7. Secret Agent Man - Al Caiola | |
| 8. Who Needs Forever - Astrud Gilberto | |
| 9. Theme From The Man From U.N.C.L.E - The Challengers | |
| 10. The Last Of The Secret Agents - Nancy Sinatra | |
| 11. Mission: Impossible - Lalo Schifrin & His Orchestra | |
| 12. Dr. Goldfoot And The Bikini Machine - The Supremes | |
| 13. Our Man Flint - Billy Strange | |
| 14. Wednesday's Child - Matt Monro | |
| 15. Get Smart - Don Adams | |
| 16. We Should've - Cleo Laine & Ray Ellington | |
| 17. The James Bond Theme - Johnny & The Hurricanes | |
| 18. Burke's Law Theme - Wynton Kelly | |
| 19. Where The Bullets Fly - Susan Maughan | |
| 20. High Wire - Brian Fahey & His Orchestra | |
| 21. Bye Bye (Theme From Peter Gunn) - Sarah Vaughan | |
| 22. Theme From Where The Spies Are - Jimmy Smith | |
| 23. The Liquidator - Shirley Bassey | |
| 24. I Spy - Roland Shaw & His Orchestra | |
| 25. Come Spy With Me - Smokey Robinson & The Miracles | |
